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第三幕
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第八章
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I Berg, I. A.(2011). Ecological aspects of the distribution of diferent autotrophic CO2 fixation pathways.Applied and environmental microbiology, 77(6) 1925-1936.
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II Ellis, R. J.(1979). Most abundant protein in the world.Trends in biochemical sciences, 4: 241–244.
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III Fuchs, G.(2011). Alternative pathways of carbon dioxide fixation: Insights into the early evolution of life?Annual review of microbiology, 65(1): 631–658; Hu, Yajing; Holden, J. F.(2006). Citric acid cycle in the hyperthermophilic archaeon Pyrobaculum islandicum grown autotrophically, heterotrophically, and mixotrophically with acetate.Journal of bacteriology, 188(12)
:4350–4355；Barbara, J.; Campbell, S.; Craig, C.(2004). Abundance of reverse tricarboxylic acid cycle genes in free-living microorganisms at deep-sea hydrothermal vents.Applied and environmental microbiology, 70(10): 6282-6289.
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IV 关于奇异变形杆菌的三羧酸循环，参见：Alteri, C. J.; Himpsl, S. D.; Engstrom, M. D.; et al.(2012). Anaerobic respira tion using a complete oxidative TCA cycle drives multicellular swarming in proteus mirabilis.Mbio, 3(6): 17-17。
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V 关于三羧酸循环在热力学和动力学上的优势，参见：Ebenhöh, O.; Heinrich, R.(2001). Evolutionary optimization of metabolic pathways. Theoretical reconstruction of the stoichiometry of ATP and NADH producing systems.Bulletin of Mathe matical Biology, 63(1): 21–55。
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VI 关于三羧酸循环和逆三羧酸循环的无机催化，参见：Zubarev, D. Y.；Rappoport, D.; Aspuru-Guzik, A.(2015). Un certainty of prebiotic scenarios: The case of the non-enzymatic reverse tricarboxylic acid cycle.Scientific reports, 5(1)
:8009；Springsteen, G.; Yerabolu, J. R.; Nelson, J.; et al.(2018). Linked cycles of oxidative decarboxylation of glyoxylate as protometa bolic analogs of the citric acid cycle.Nature communications, 9(91)；Muchowska, K. B.; Varma, S. J.; Chevallot-Beroux, E.; et al.(2017). Metals promote sequences of the reverse Krebs cycle.Nature ecology & evolution, 1(11): 1716–1721.
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VII 关于黑烟囱上的绿硫菌，参见：Beatty, J. T.; Overmann, J.; Lince, M. T.; et al.(2005). An obligately photosynthetic bacterial anaerobe from a deep-sea hydrothermal vent.Proceedings of the National Academy of Sciences, 102(26): 9306–9310; Martinez-Planells, A.; Arellano, J. B.; Borrego, C. M.; et al.(2002). Determination of the topography and biometry of chloro somes by atomic force microscopy.Photosynthesis research, 71(1–2): 83–90。
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VIII 关于光化学催化的逆三羧酸循环实验，参见：Zhang, Xiang V.; Martin, S. T.(2006). Driving parts of krebs cycle in reverse through mineral photochemistry.Journal of the American Chemical Society, 128(50): 16032-16033.
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IX 金属单质催化还原二氧化碳生成乙酰辅酶A路径产物的论文，参见：Varma, S. J.; Muchowska, K. B.; Chatelain,P.; et al. Native iron reduces CO₂ to intermediates and end-products of the acetyl-CoA pathway.Nature Ecology & Evolution, 2: 1019–1024。
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第九章
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I 数据依据CRC Handbook of Chemistry and Physics, 2009, pp.5-42, 90th ed., Lide。
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II 二人合作提出白烟囱假说的论文，参见：Martin, W.; Russell, M.(2003). On the origins of cells: a hypothesis for the evolutionary transitions from abiotic geochemistry to chemoautotrophic prokaryotes, and from prokaryotes to nucleated cells.Philosophical transactions of The Royal Society B Biological Sciences, 58(1429)
:59-83。
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III B. J. Skinner, R. C. Erd, and F. S. Grimaldi, American Mineralogist 49, 543 (1964).
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IV Anthony, J. W.; Bideaux, R. A.; Bladh, K. W.; Nichols, M. C., eds. (1990).Handbook of Mineralogy(Vol I). Chantilly, VA,US: Mineralogical Society of America; Lefèvre, C. T.; Menguy, N.; Abreu, F.; et al.(2011). A cultured greigite-producing mag netotactic bacterium in a novel group of sulfate-reducing bacteria.Science, 334(6063): 1720-1723; Gorlas, A.; Jacquemot, P.; Guigner, J.-M.; Gill, S.; et al.(2018). Greigite nanocrystals produced by hyperthermophilic archaea of Thermococcales order.PLoS ONE, 13(8): e0201549.
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V 关于鳞角腹足螺的“铁甲”，参见：Yao, Haimin; Dao, Ming; Imholt, T.; Huang, J.; et al.(2010). Protection mechanisms of the iron-plated armor of a deep-sea hydrothermal vent gastropod.PNAS, 107 (3): 987–992。
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VI White, L. M.; Bhartia, R.; Stucky, G.; et al.(2015). Mackinawite and greigite in ancient alkaline hydrothermal chimneys: Identifying potential key catalysts for emergent life.Earth and planetary science letters, 430: 105-114.
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VII 关于铁复硫矿催化乙酰辅酶A路径，参见：Roldan, A.; Hollingsworth, N.; Rofey, A.; et al.(2015). Bio-inspired CO2 conversion by iron sulfide catalysts under sustainable conditions,Chemical communications, 51(35)
:7501–7504。
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VIII 实验论文参见：Preiner, M.; Igarashi, K.; Muchowska, K. B.; et al.(2020) A hydrogen-dependent geochemical analogue of primordial carbon and energy metabolism. Nature Ecology & Evolution, 4: 534–542。
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IX Russell, M. J.; Nitschke, W.(2017). Methane: Fuel or exhaust at the emergence of life?Astrobiology, 17(10): 1053–1066.
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X 二氧化碳被氢气还原成甲酸，参见：Moret, S.; Dyson, P. J.; Laurenczy, G.(2014). Direct synthesis of formic acid from carbon dioxide by hydrogenation in acidic media.Nature communications, 5: 4017。
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XI Herschy, B.; Whicher, A.; Camprubi, E.; et al.(2014). An origin-of-life reactor to simulate alkaline hydrothermal vents.Journal of molecular evolution, 79(5-6): 213–227;Volbeda, A.; Fontecilla-Camps J. C.(2006). Catalytic nickel–iron–sulfur clusters: from minerals to enzymes. In: Simonneaux, G.(eds).Bioorganometallic Chemistry.Topics in organometallic chemistry, 17: 57–82. Berlin, Germany
:Springer.
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XII 实验论文，参见：Herschy, B.; Whicher, A.; Camprubi, E.; et al.(2014). An origin-of-life reactor to simulate alkaline hy drothermal vents.Journal of molecular evolution, 79(5-6): 213–227。
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XIII 在这个实验最终发表后的论文：Vasiliadou, R.; Dimov, N.; Szita, N.; et al.(2019). Possible mechanisms of CO2 reduc tion by H2 via prebiotic vectorial electrochemistry.Interface focus, 9(6)。
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